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XIAOMI SU7 brand new car unboxing ceremony !
XIAOMI SU7 brand new car unboxing ceremony !
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In their series “Fossil Fools” and a new series “The Other Petrostates” today the Guardian published an article starting with the following two…
In their series “Fossil Fools” and a new series “The Other Petrostates” today the Guardian published an article starting with the following two…
Posted by Brian Goodall
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A few words from newly elected South Derbyshire labour MP - Samantha Niblett MP. Thank you for coming along and showing your support at the…
A few words from newly elected South Derbyshire labour MP - Samantha Niblett MP. Thank you for coming along and showing your support at the…
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Experience & Education
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First Garden City Consulting
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Publications
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Ultrahigh Tg Epoxy Thermosets Based on Insertion Polynorbornenes
Macromolecules, Article ASAP. DOI: 10.1021/acs.macromol.5b02648
Thermosetting materials (thermosets) are widely used organic materials derived from 3D-network forming monomers. Achieving high glass transition temperature (Tg) thermosets is often a challenging task due to the complexity of designing efficiently and cheaply monomers which are rigid enough to prevent molecular motions within the thermoset. We report here a very simple route to prepare epoxy thermosets with Tg as high as 350 °C, based on insertion polynorbornenes. The epoxy monomer…
Thermosetting materials (thermosets) are widely used organic materials derived from 3D-network forming monomers. Achieving high glass transition temperature (Tg) thermosets is often a challenging task due to the complexity of designing efficiently and cheaply monomers which are rigid enough to prevent molecular motions within the thermoset. We report here a very simple route to prepare epoxy thermosets with Tg as high as 350 °C, based on insertion polynorbornenes. The epoxy monomer (PNBE(epoxy)) is prepared by the epoxidation of poly(5-vinylnorbornene) obtained by catalytic insertion polymerization of 5-vinylnorbornene. PNBE(epoxy) can be cross-linked with simple biosourced compounds. Alternatively, polar insertion polynorbornene can also be used as cross-linker in the formulation of an epoxy resin, once again resulting in epoxy resins with Tg higher than 300 °C and devoid of degradation at this temperature. Thus, this study clearly demonstrates the viability of catalytic polymerization to access epoxy thermosets with ultrahigh Tg.
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“Techno-economics of microalgae production and conversion to refinery-ready oil with co-product credits”
Biofuels, Bioprod. Bioref. 9:760–777 (2015); DOI: 10.1002/bbb.1610
The economics of the production of hydrotreated algal oil (HTAO) along with co-production
of animal feed and nutraceuticals (omega-3 oils) was explored. Base case calculations were for commercial scale production of 10,000 barrels per day of HTAO with nutraceuticals claiming only 0.05% of the raw algae oil (AO). The sensitivity of economics to critical parameters was studied.We
gratefully acknowledge that this work was funded by DOE contract DE-EE0006063.Other authors -
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“Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination-Insertion Copolymerization of Polar Vinyl Monomers,”
Acc. Chem. Res., 2013, 46, 1438. DOI: 10.1021/ar300256h
Ligands, Lewis bases that coordinate to the metal center in a complex, can completely change the catalytic behavior of the metal center. In this Account, we summarize new reactions enabled by a single class of ligands, phosphinesulfonates (ortho-phosphinobenzenesulfonates). Using their palladium complexes, we have developed four unusual reactions, and three of these have produced novel types of polymers.
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Patents
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Processes for Producing Omega-3 containing Compositions from Algae and Related Extractions
Issued US 11,730,782
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Medical Compositions with Omega-3 Containing Excipients
Issued US 11,638,731
A composition comprising a concentration of total lipids, wherein at least 20% of the total lipids concentration by weight % comprises a polar lipids fraction, with greater than about 30% by weight % of the polar lipids fraction comprising glycolipids, and wherein the composition comprises no greater than 4% of its weight % as chlorophyll concentration, and formulations and medical compositions including the lipids-containing composition.
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Omega-3 containing compositions
Issued US 11,298,387
The present disclosure relates to a bioavailable , oil composition wherein at least 20 % by weight % of its total lipids content comprises polar lipids such as glycolipids or phospholipids , at least 30 weight % of its polar lipids comprises glycolipids , and no more than 4 % by weight % of the oil composition is made up of chlorophyll species . Formulations containing and methods for producing said oil compositions from algal oils or extracts are also disclosed .
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Methods of preparing oil compositions for fuel refining
Issued US 9,145,528
Disclosed herein are methods and systems for upgrading (for example, removing heteroatoms, metals, or metalloids) an oil composition derived or extracted from a biomass. The upgraded oil composition can be used to make a desired product, for example, a fuel product.
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Algae extraction process
Issued US 8,591,912
A method of extracting oil from algae by drying algae paste to a predetermined moisture content, contacting the algae paste with a polar solvent to make an algae-solvent solution and extracting oils from the algae paste into a solvent-oil solution, and separating extracted algae from the solvent-oil solution. An oil of whole and unhydrolyzed phospholipids, whole and unhydrolyzed glycolipids, lysolipids, and carotenoids extracted by the above method. An omega-3 fatty acid of docosahexanoic acids…
A method of extracting oil from algae by drying algae paste to a predetermined moisture content, contacting the algae paste with a polar solvent to make an algae-solvent solution and extracting oils from the algae paste into a solvent-oil solution, and separating extracted algae from the solvent-oil solution. An oil of whole and unhydrolyzed phospholipids, whole and unhydrolyzed glycolipids, lysolipids, and carotenoids extracted by the above method. An omega-3 fatty acid of docosahexanoic acids (DHAs) and eicosapentaenoic acids (EPAs) extracted from the above method. Isolated nutraceutical grade and pharmaceutical grade oil derived from algae and being free of toxins extracted by the above method. Isolated oil derived from algae including at least one omega-3 fatty acid of DHA and EPA at least partially in the form of whole and unhydrolyzed phospholipids and whole and unhydrolyzed glycolipids extracted by the above method.
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A Catalyst Composition and its Preparation and Use for Preparing Polymers from Ethylenically Unsaturated Monomers
US 7,172,986
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A Catalyst Composition and its Preparation and Use for Preparing Polymers from Ethylenically Unsaturated Monomers
US 7,087,687
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A Catalyst Composition and its Preparation and Use for Preparing Polymers from Ethylenically Unsaturated Monomers
US 7,435,701
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A Process for the Preparation of Aromatic Ureas
EU 395144
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A Process for the Preparation of N-aryl-N'-acylureas
EU 398404
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A Process for the Preparation of Phenylcarbamates
EU 393789
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Addition Polymers Derived from Norbornene-Functional Monomers and Process Therefor
US 5,571,881
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Addition Polymers Derived from Norbornene-Functional Monomers and Process Therefor
US 5,569,730
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Addition Polymers Derived from Norbornene-Functional Monomers and Process Therefor
US 5,741,869
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Addition Polymers Derived from Norbornene-Functional Monomers and Process Therefor
US 5,741,869
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Addition Polymers of Polycycloolefins Containing Functional Substituents
US 5,705,503
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Addition Polymers of Polycycloolefins Containing Silyl Functional Group
US 5,912,313
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Addition Polymers of Polycycloolefins Containing Silyl Functional Groups
US 6,031,058
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Aldehyde-Telechelic Polyisobutylenes, Catalytic Method for Preparing the Same with High Conversion and Selectivity, and Block Copolymers Made Therefrom
US 5,442,015
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Aldehyde-Telechelic Polyisobutylenes, Catalytic Method for Preparing the Same with High Conversion and Selectivity, and Block Copolymers Made Therefrom
US 5,340,881
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Blends and alloys of polycyclic polymers
US 6,649,707
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Blends and alloys of polycyclic polymers
US 6,294,616
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Catalyst Complexes for Polymerization and Co-Polymerization of Cyclic Olefins
US 7,041,758
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Catalyst Components for Polymerization of Olefins
US 4,419,501
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Catalyst and Methods for Polymerizing Cycloolefins
US 6,455,650
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Catalyst and Process for Preparing Oligomers of alpha-Methylstyrene
US 6,441,260
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Catalyst and methods for polymerizing cycloolefins
US 6,825,307
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Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
US 7,199,074
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Coated Reinforcing Material
EU 424833
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Copolymerization catalyst and process for making impact resistant ethylene-propylene polymers
US 4,543,389
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Dimerization of 1-Alkenes
US 4,252,987
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Dissolution Rate Modifiers for Photoresist Compositions
US 7,422,836
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Extraction of Transition Metals from Organic Solutions
US 4,680,168
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Heteropolymetallate Metathesis Catalysts for Cycloolefin Polymerization
US 4,923,936
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Homopolymers and copolymers of cationically polymerizable monomers and method of their preparation
US 5,677,405
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Hydrocarbylhaloaluminoxane
EU 2003082466
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In Mold Addition Polymerization of Norbornene-Type Monomers Using Group 10 Metal Complexes
US 6,350,832
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In Mold Addition Polymerization of Norbornene-Type Monomers Using Group 10 Metal Complexes
US 6,936,672
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Ionic Aluminoxanate Compositions and their use in Catalysis
EU 2003082879
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Ligand Synthesis
US 7,339,075
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Method for the preparation of copolymers of ethylene and norbornene-type monomers with cationic palladium catalysts
US 6,265,506
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Method for the preparation of copolymers of ethylene and norbornene-type monomers with cationic palladium catalysts
US 6,265,506
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Method for the preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
US 6,197,984
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Method for the preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts
US 5,929,181
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Methods and Systems for Biofuel Production
US 20100297749
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Olefin Polymerization Catalyst Compositions
US 4,400,302
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Olefin Polymerization Catalyst Compositions
US 4,393,182
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Olefin Polymerization Catalyst Compositions
US 4,329,253
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Olefin Polymerization Catalyst and Polymerization Process
US 7,098,278
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Olefin Polymerization Catalysts
US 4,548,915
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Olefin polymerization catalyst and polymerization process
US 7,037,987
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Olefin polymerization process utilizing a combination of selectivity control agents
US 4,563,512
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Oxide co-catalysts in ring opening polymerization of polycycloolefins
US 5,155,188
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Photodefinable dielectric compositions comprising polycyclic polymers
US 6,121,340
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Photoresist compositions comprising polycyclic polymer with acid labile pendant groups
US 6,136,499
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Photoresist compositions comprising polycyclic polymer with acid-labile pendant groups
US 6,723,486
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Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US 6,790,579
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Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US 6,232,417
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Photoresist compositions comprising polycyclic polymers with acid labile pendant groups
US 6,136,499
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Photosensitive Compositions based on Polycyclic Polymers
US 7,022,790
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Polycyclic Copolymer Compositions
US 6,303,724
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Polycyclic Polymers containing Pendant Cyclic Anhydride Groups and Photoresist Compositions
US 6,525,153
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Polycyclic polymers containing pendant cyclic anhydride groups
US 6,525,153
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Polycyclic resist compositions with increased etch resistance
US 6,147,177
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Polymerization of acyclic aliphatic olefins
US 7,671,150
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Polymerized Cycloolefins using Transition Metal Catalyst and End Products Thereof
US 6,903,171
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Preparation of Conjugated Dienes
US 4,943,670
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Preparation of Herbicidal Phenylureas
EU 319111
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Preparation of linear ethylene-acrylate copolymers with palladium catalysts and free radical scavengers
US 7,524,912
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Process for Making Polymers Containing a Norbornene Repeating Unit by Addition Polymerization Using an Organo (Nickel or Palladium) Complex
US 5,468,819
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Process for Making Polymers containing Pendant Cyclic Anhydride Groups
US 6,649,714
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Process for Purification of Alkenyl Aromatic Compounds Containing a Benzaldehyde Impurity
US 4,933,499
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Process for sequentially copolymerizing propylene-ethylene copolymers and catalyst therefor
US 4,520,163
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Process for the Hydroformylation of Olefins Using Rhodium-based Catalysts
EU 309056
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Process for the preparation of polyisoprene
US 4,600,757
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Processes for making polymers containing pendant cyclic anhydride groups
US 6,649,714
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Processes of making polymers containing pendant cyclic anhydride groups with nickel-ligand catalyst
US 6,528,598
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Processes of making polymers containing pendant cyclic anhydride groups with nickel-ligand catalyst
US 6,528,598
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Reaction Injection Molding (RIM) of Methyl (Meth) Acrylate and Related Monomers using Group IV Catalysts
US 5,668,234
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Recovery of Transition Metals from Aqueous Solutions
US 4,880,546
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Removing Contaminants from a Liquid Titanium Chloride Phase
US 4,683,215
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Ring opening polymerization with organophosphonium and organoarsonium metathesis catalysts
US 4,923,939
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SYSTEMS, METHODS AND APPARATUSES FOR DEWATERING, FLOCCULATING AND HARVESTING ALGAE CELLS
US 20120129244
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Single Site Catalyst Complexes
US 7,833,927
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Stereospecific Polymerization of an Alpha-Olefin and an Alpha-Olefin Polymerization Catalyst System
US 4,478,989
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Substantially Linear Polymers and Methods for Making the Same
US 7,524,905
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Substantially linear polymers and methods of making and using same
US 7,635,739
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Synthesis of Molybdenum and Tungsten Complexes
US 5,142,073
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System and Process for Producing Biodiesel
US 20080282606
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Languages
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Dutch
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Brant Cooper came to me in a dream last week. I was performing on stage, a one man show, a black box thing, about to bleed out with emotion in front…
Brant Cooper came to me in a dream last week. I was performing on stage, a one man show, a black box thing, about to bleed out with emotion in front…
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This research study led by Aleix Sala-Vila et al, adds to the growing body of evidence that diet rich in omega-3 fatty acids, from both plant and…
This research study led by Aleix Sala-Vila et al, adds to the growing body of evidence that diet rich in omega-3 fatty acids, from both plant and…
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There is still HOPE 👍💪💚🌍🙏 New research suggests plants might be able to absorb more CO2 from human activities than previously expected.
There is still HOPE 👍💪💚🌍🙏 New research suggests plants might be able to absorb more CO2 from human activities than previously expected.
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If Elon follows through on donating $45 million a month from now until the election, he'd only be spending about 0.06% of his total wealth. It…
If Elon follows through on donating $45 million a month from now until the election, he'd only be spending about 0.06% of his total wealth. It…
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A rude awakening coming soon for the EU, UK, NATO and Ukraine.
A rude awakening coming soon for the EU, UK, NATO and Ukraine.
Shared by Brian Goodall
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“A death potion for the river.” ☠️ The impact of cheap chicken combined with dishonest and irresponsible water companies releasing raw sewage into…
“A death potion for the river.” ☠️ The impact of cheap chicken combined with dishonest and irresponsible water companies releasing raw sewage into…
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Thank you very much for including me iNHouse Communications ☺️🙌🏻🌹 #WomenInTech #WomenInPolitics #SouthDerbyshire
Thank you very much for including me iNHouse Communications ☺️🙌🏻🌹 #WomenInTech #WomenInPolitics #SouthDerbyshire
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I am excited to be working with Mediaplanet again on the 'Opportunities in STEM 2024' campaign, which will launch today in the New Scientist Magazine…
I am excited to be working with Mediaplanet again on the 'Opportunities in STEM 2024' campaign, which will launch today in the New Scientist Magazine…
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